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01-05-2018
Physics

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Show that the difference in volume across a first-order phase boundary is given
by ∆V = −∆F/P.

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savagekyrie3 savagekyrie3

01-05-2018

G as a function of P at constant T for liquid and solid phases. As we can see from the fundamental equation, dG = VdP – SdT, the free energy of a phase increases with pressure: If the two phases have different molar volumes

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